Sr–Nd isotopes and geochemistry of the infrastructural rocks in the Meatiq and Hafafit core complexes, Eastern Desert, Egypt: Evidence for involvement of pre-Neoproterozoic crust in the growth of Arabian–Nubian Shield

Abstract Meatiq and Hafafit core complexes are large swells in the Eastern Desert of Egypt, comprising two major tectono‐stratigraphic units or tiers. The lower (infrastructure) unit is composed of variably cataclased gneissose granites and high‐grade gneisses and schists. It is structurally overlain by Pan–African ophiolitic mélange nappes (the higher unit). The two units are separated by a low‐angle sole thrust, along which mylonites are developed. Major and trace element data indicate formation of the gneissose granites in both volcanic arc and within‐plate settings. Nevertheless, all analyzed gneissose granites and other infrastructural rocks, exhibit low initial ratios (Sr_i) (<0.7027), positive ε_Nd(t) (+4.9 to +10.3) and Neoproterozoic Nd model age (T_DM) (592–831 Ma for the gneissose granite samples). Although these values are compatible with other parts of the Arabian– Nubian Shield considered to be juvenile, the ε_Nd(t) values and several incompatible element ratios of the gneissose granites are too low to be derived from a mantle source without contribution from an older continental crust. Our geological, Sr–Nd isotopic and chemical data combined with the published zircon ages indicate the existence of a pre‐Neoproterozoic continent in the Eastern Desert that started to break up at ca 800 Ma. Rifting and subsequent events caused the formation of oceanic crust and emplacement within‐plate alkali basalts in the hinterland domains of the old continent. The emplacement of basaltic magma might have triggered melting of lower crust in the old continent and resulted in emplacement of the within‐plate granite masses between 700 Ma and 626 Ma. The granite masses and other rocks in the old continent have been subjected to deformation during the over‐thrusting of Pan–African nappes, probably because of the oblique convergence between East and West Gondwanaland. Rb–Sr isotopes of the gneissose granites in both Meatiq and Hafafit core complexes defines an isochron age of 619 ± 25 Ma with Sr_i of 0.7009 ± 0.0017 and mean squares of weighted deviates = 2.0. We interpret this age as the date of thrusting of the Pan–African nappes in the Eastern Desert. Continued oblique convergence between East and West Gondwanaland could have resulted in the formation northwest–southeast‐trending Meatiq and Hafafit anticlinoriums.     

Exploration of the extension of two lava tubes,faults and dikes using very low frequency-electromagnetic technique in NE Jordan

The very low frequency-electromagnetic (VLF-EM) technique was used to delineate two sub-parallel lava tubes, faults and dikes in Umm El-Quttein area, NE Jordan. The investigation of the lava tubes was conducted through 22 VLF-EM profiles across lava strike; the length of profiles ranged from 700 to 1700 m. The lava tubes outcrop at two sites: Azzam cave and Al-Howa tunnel, characterized by slightly weathered basalt, columnar joints and fissure zones; qualitative interpretation of Fraser and Karous-Hjelt maps differentiate those zones as linear, elongated and circular anomalous zones. The 2-D tipper inversion of VLF-EM data and resistivity imaging had the potential to screen out three anomalous zones of likely resistivity contrast: the lava tube body with resistivity over 2500 Θ·m, the fractured zones with resistivity less than 500 Θ·m, and the host vesicular basalt with resistivity of 1500 Θ·m. The strike of lava tubes varied from SW to NE direction with depth less than 20 m and width from 10 to 30 m.     

INDUCED POLARIZATION,A METHOD TO STUDY WATER-COLLECTING PROPERTIES OF ROCKS*

During the last decade many hypotheses were suggested to explain the phenomenon of induced electrical polarization in ionic conductive media. The most reliable of these is Fredricksberg's. Fredricksberg (1962) supposed that the pore spaces of a rock is composed of successively narrow (active zones) and wide (inactive zones). He simulated these pore spaces by a synthetic material that has an extremely high resistance. The pore spaces were generally in tube forms which exhibited some constrictions. He saturated these tubes with an electrolyte of a given concentration. An electric current was passed through this model. He observed an induced polarization voltage after current interruption. He attributed the formation of this voltage to a concentration gradient which took place due to the presence of excess charges in the active zones. Fredricksberg introduced a parameter (9) which described the relation among the lengths and cross sectional areas of the wide zones, the number of ions within each zone after current interruption with the recorded polarizability. The aim of this work is to correlate Fredricksberg's parameter with a parameter determined for natural rocks and to show experimentally the validity of this hypothesis when applying for some varieties of sandstones and volcanic rocks. The new parameter will help to evaluate a relationship between the polarizability and the water-collecting properties of rocks. Herein, we used the tortuosity T of sandstone samples instead of the parameter φ which was used by Fredricksberg to represent the pore geometry within his model (tortuosity of the passes within the model). It was shown that both φ and T have the same relationship with the polarizability ν of the rock samples and if φ or T have very low or very high values the polarizability ν tends to its minimum value, i.e. the curve representing the relation between ν and T has a maximum point corresponding to an intermediate value of T. This result supports Fredricksberg's hypothesis and confirm his results on synthetic models. For volcanic rocks the formation factor F was used since it was difficult to determine the porosity of the samples and consequently to calculate the tortuosity T as for sandstone samples. Experimental results confirm those obtained from sandstone. The grain constituents of sandstone samples were represented on equilateral triangle and the magnitude of induced polarization ν of each sample was deduced and represented on this triangle. Equipolarizability values ν drawn on this triangle showed that TJ will increase as the silty fractions of the rock increase, where the center of this triangle (represents minimum porosity) has polarizability less than 0.25%. An attempt was made to determine the coefficient of anisotropy of volcanic rock samples using the induced polarization method. For this reason the polarizability was deduced by measuring the induced polarization voltage for two perpendicular directions in a fractured cubes of andesitic basalt samples the coefficient of anisotropy was found to be equal 1.18.     

Speaking of the devil: a systematic literature review on community preparedness for earthquakes

Natural Hazards - Community preparedness in facing natural hazards such as earthquakes is extremely important. Although there are numerous studies on community preparedness for earthquakes, the...     

ESR and Th/U dating of speleothems from Aladağlar Mountain Range (AMR) in Turkey

Electron spin resonance (ESR) and ²³⁰Th/²³⁴U ages of speleothem samples collected from karstic caves located around 3000 m elevation in the Alada?lar Mountain Range (AMR), south-central Turkey, were determined in order to provide new insight and information regarding late Pleistocene climate. ESR ages were validated with the ²³⁰Th/²³⁴U ages of test samples. The ESR ages of 21 different layers of six speleothem samples were found to range mostly between about 59 and 4 ka, which cover the Marine Oxygen Isotope Stages (MIS) MIS 3 to MIS 1. Among all, only six layers appear to have deposited during MIS 8 and 5. Most of the samples dated were deposited during the late glacial stage (MIS 2). It appears that a cooler climate with a perennial and steady recharge was more conducive to speleothem development rather than a warmer climate with seasonal recharge in the AMR during the late Quaternary. This argument supports previous findings that suggest a two -fold increase in last glacial maximum mean precipitation in Turkey with respect to the present value.     

Molybdenum isotope evidence for mild environmental oxygenation before the Great Oxidation Event

We use the molybdenum isotope paleoredox proxy to look for evidence of small amounts of O₂ in the environment ∼50 Ma before the Great Oxidation Event (GOE) in a high resolution profile from the ∼2.5 Ga Mt. McRae Shale. The molybdenum isotope compositions (δ^98/95Mo) from samples throughout the sequence span a range from 0.99‰ to 1.86‰. All samples have heavier δ^98/95Mo compared to average upper continental crust. In addition, the upper (S1) and lower (S2) black shale units within the Mt. McRae Shale exhibit systematic differences in average isotopic compositions and distinct patterns of δ^98/95Mo variation. Heavier δ^98/95Mo values occur in the S1 unit, where δ^98/95Mo correlates with Mo enrichments. In the S2 unit, δ^98/95Mo is not as heavy and is relatively invariant.Based on sedimentary Fe proxies we infer that S1 sediments were deposited under euxinic conditions, so that Mo removal from bottom waters was likely quantitative. Thus, δ^98/95Mo in this interval likely records coeval seawater. The lighter δ^98/95Mo values in the S2 unit may indicate a less fractionated ocean Mo inventory relative to the S1 unit. However, sedimentary Fe proxies suggest that S2 sediments accumulated under a water column that was ferruginous rather than euxinic, raising the possibility of non-quantitative Mo scavenging and hence an expressed δ^98/95Mo fractionation relative to coeval seawater. Because any associated fractionations during this process would have favored the light isotope in sediments, the lighter δ^98/95Mo values in the S2 unit represent a lower limit on the value in contemporaneous seawater.After evaluating a range of hypotheses, we conclude that the isotopically heavy δ^98/95Mo values seen throughout the Mt. McRae Shale likely reflect the effects of oxidative weathering and adsorption of Mo to oxide mineral surfaces on land or in surface oceans. The extent of environmental oxygenation in either unit is difficult to assess due to uncertainties in the global Mo isotope budget. Because of the small ocean Mo inventory in the Late Archean, documented by low concentrations of Mo and low Mo/TOC, the extent of oxygenation required to account for the observed fractionations is much smaller than in modern oceans. However, when juxtaposed against the record of δ^98/95Mo through time, our findings provide further evidence of the onset of environmental oxygenation before the GOE.     

Geochemistry,provenance, and metamorphic evolution of Gabal Samra Neoproterozoic metapelites,Sinai, Egypt

Metapelites are exposed at Wadi Ba’ba, east of Abu Zenima city; represent the northwestern extension of the Fieran-Solaf Metamorphic Complex, Sinai Peninsula, Egypt. The metapelites are characterized by qtz + pl (An_24–28) + bt + grt ± crd ± sil mineral assemblage, indicating upper amphibolite facies with peak metamorphic conditions of 700 °C and pressures of 7 kbar, as determined by conventional geothermobarometeric methods. This resulted in incipient migmatization, forms patches of leucosomes and melanosomes. Geochemical investigation indicates that the precursor sediments of the metapelites had been deposited as immature Fe-rich shales from source materials of dominantly intermediate composition. Source area exhibited weak to moderate chemical weathering in a tectonically active continental marginal basin within a continental-arc system. A strong shallow-dipping foliation, characterizing the metapelites, was folded around an open antiform with sub-horizontal south plunging hinge.Phase equilibria calculations in the KFMASH system indicate that the peak metamorphic conditions formed at 730–750 °C and 6.8–7.9 kbar. This was followed by a retrogression formed at 770–785 °C and 3.9–4.5 kbar. Hence, this implies an isothermal decompression and rapid exhumation of the metapelites from depth (25–29 km) in the lower crustal level at peak conditions, continuous to include shallow to middle crustal level (14–17 km), at overprint retrograde conditions. Subsequent isobaric cooling took place at 720–750 °C and 3.6–4.5 kbar. The resulting isothermal decompression followed by isobaric cooling clockwise P–T path of the metapelites is more likely, in which the high-temperatures attained maximum conditions during isothermal decompression were enhanced by heat flux, due to the presence of an active magmatic arc that formed on top of subducting young lithosphere. This is supported by a moderate geothermal gradient of 27–43 °C/km and dating compatibility of the Sinai granitoids and the metamorphic complexes. The P–T path segment records the tectonothermal histories of crustal thickening as a result of the East and West Gondwana collision at the metamorphic peak. This was subsequent by extensional and crustal thinning with syn-metamorphic magmatic intrusions, during P–T path retrogression, which resulted in the final assembly of the Arabian–Nubian Shield during Neoproterozoic.     

Patterns in the local assembly of Egyptian rodent faunas: Co-occurrence and nestedness

We studied co-occurrence patterns of 29 rodents across 308 sites in Egypt to evaluate spatial variation and non-randomness in community assembly (co-occurrence and nestedness). There was strong evidence for negative species association in the entire fauna. Negative associations can be traced to habitat segregation among species, the discreteness of habitats, low species richness at local assemblages due to aridity and low primary productivity, and allopatry of sibling species. Nevertheless, high degree of nestedness characterizes the entire collection, as tested by BINMATNEST and Aninhado. Species ranks in the packed matrix were significantly correlated with incidence, total abundance, number of coexisting species, total number of species combinations, and range size. Analyses of the assemblages by region and sampling intensity using Aninhado simulations confirmed the nestedness for the whole fauna and showed little or no nested structure in species incidences.Egyptian rodent faunas appear to be structured by a dynamic interplay of biotic and abiotic factors operating on distinct sets of species with shared habitat preferences and requirements. Local assembly patterns may result from interspecific interactions coupled with aridity and low productivity, habitat requirements, and historical factors. The harsh conditions of these arid regions led to the prevalence of species exclusion.     

Taphonomic and diagenetic aspects of the Late Cretaceous Libycoceras ismaeli (Zittel) from Northern Jordan

Taphonomy and diagenesis of the ammonoid Libycoceras ismaeli (Zittel) have been approached in order to interpret the post-mortem depositional history during the Late Cretaceous of Jordan based on the comparative analysis of composition and taphonomy. The Campanian–Maastrichtian Al-Hisa Phosphorite Formation is exposed in northwestern and central Jordan is rich in cephalopods. It consists of alternating thin-bedded limestone, more or less silicified or calcified phosphorite layers, thick- and cross-bedded oyster lumachells, and lenses and layers of minable phosphate. The sphenodiscid ammonite L. ismaeli (Zittel) predominantly occurs in the middle part of this formation. L. ismaeli is associated with different nautiloid and baculitid species. The mode of occurrence of the studied ammonoids suggesting that they are best interpreted to been nektobenthic, not nektoplanktic. Taphonomic and diagenetic studies of transversely sliced specimens were carried out by means of polarizing and scanning electron microscope.     

Assessing the engineering properties of concrete made with fine dune sands: an experimental study

Sand dunes cover an area of 16.6% of the total area of Egypt. This paper presents the results of an extensive laboratory testing that was carried out to determine the engineering properties of concrete. The concrete fine aggregate is fine dune sands obtained from three sites in the Kharga Oasis, Western Desert, Egypt. All samples were classified as poorly graded sand according to the Unified Soil Classification system. Fineness modulus values of the studied dune sands range from 0.89 to 0.97. The percentage of sulfates and chlorides are very low and nearly negligible. Sodium and calcium hydroxides were recorded in some samples with scarce concentration. Organic impurities were not recorded. The degree of workability of the studied dune sands ranged from low to medium, which are suitable for normal reinforced work without vibration and heavily reinforced section with vibration. The measured compressive strength of concrete decreases with increasing dune sand content.